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In 1704, Whitworth was appointed as Ambassador Extraordinary to Russia.
The second chief of mission, Joseph C. Green, was appointed as an envoy but promoted to as Ambassador Extraordinary and Plenipotentiary, as the Legation Amman was raised to embassy status on August 27, 1952.
Vasile Sturza (born 13 March 1953 in Căbăieşti, Călăraşi district) was the Ambassador Extraordinary and Plenipotentiary of the Republic of Moldova to the Russian Federation.
He was the Ambassador Extraordinary and Plenipotentiary first to the United Arab Republic in 1968, to Yugoslavia, Ethopia, and Lebanon in 1969, and to Indonesia from 1974 to 1978.
He was also Ambassador Extraordinary and Plenipotentiary of Pakistan to Rwanda, Ethiopia and Uganda under the Pakistan Peoples Party (PPP) government of Benazir Bhutto (1989–90).
He was concurrently appointed as Ambassador Extraordinary and Plenipotentiary to Mali and Niger then to Upper Volta and to the Ivory Coast.
Katalin Bogyay is the President of the General Conference of UNESCO (2011–2013) and the Ambassador Extraordinary and Plenipotentiary and Permanent Delegate of Hungary to UNESCO (2009-).
He took on duties outside of Nepal later in life, appointed to a six-year term as a member of Rajya Sabha in 1963 and later serving as the Ambassador Extraordinary and Plenipotentiary of Nepal to the Court of St. James's from 1973 to 1977.
In 2009 Yurii Kostenko was appointed Ambassador Extraordinary and Plenipotentiary of Ukraine to China, and Skyrda has been living and working there to the present (2011).
In 1988 Liudmyla Skyrda went to Vienna, where her husband – Ukrainian diplomat Yurii Kostenko hold rank of the Permanent Representative of Ukraine to International Organizations, soon he became the first Ambassador Extraordinary and Plenipotentiary of independent Ukraine in the Republic of Austria.
Luis Miguel Valdivieso Montano became the Ambassador Extraordinary and Plenipotentiary of Peru in the United States on February 17, 2009, after being Minister of Economy and Finance Peru from mid – 2008 until January 2009.
Prince Nikolaus of Liechtenstein - Liechtenstein's Ambassador Extraordinary and Plenipotentiary to the Holy See