Wynne joined the Canterbury Association on 25 October 1849, and on 8 November of that year joined the management committee.
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Ashburton was named by the surveyor Captain Joseph Thomas of the New Zealand Land Association, after Francis Baring, 3rd Baron Ashburton, who was a member of the Canterbury Association.
In the following decade, land alongside Duvauchelle Bay was leased from the Canterbury Association by British settlers, including William Augustus Gordon, who was the brother of Charles George Gordon, the famous soldier and colonial administrator, known as "Gordon of Khartoum" after his death.
In 1849, the chief surveyor of the Canterbury Association, Joseph Thomas, gave the river the name Courtenay River after Lord Courtenay, but it lapsed into disuse.
The Ashburton River in New Zealand and the town of the same name located on the river were named by the chief surveyor of the Canterbury Association, Joseph Thomas, after Lord Ashburton.
In 1862 James Edward FitzGerald of ‘The Springs’ subdivided some of his freehold land for the new township of Lincoln, named after the Earl of Lincoln, a foundation member of the Canterbury Association and from 1851 a member of the management committee.
Together with Lord Lyttelton, Lord Richard Cavendish and Edward Gibbon Wakefield, he guaranteed ₤15,000 to the Canterbury Association in April 1850, which saved it from financial collapse.