In 1815, after the end of the Napoleonic Wars, Duchesne followed Barat's instructions and established a Convent of the Sacred Heart in Paris, where she both opened a school and became the Mistress of novices.
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She graduated with a scholarship from the Convent of the Sacred Heart in Greenwich, Connecticut.
The Society of the Helpers of the Holy Souls was founded by Blessed Eugenia Smet, A.P. She was educated at the Convent of the Sacred Heart in Lille, distinguishing herself by intellectual acquirements and striking traits of devotion to the souls in Purgatory.
Vincent (Séamus) (1930–2005), a Benedictine priest at Glenstal Abbey, Sister Íde of the Convent of The Sacred Heart, Mount Anville, Dublin, Oonagh (who married the Irish artist Patrick Swift), Cora who married the politician, Seán Dunne, T.D. When Kathleen was an undergraduate at University College Dublin, she was introduced to the future Dr. Dermod Devane of Limerick.
In 1936 she was sent to England to be educated at the Convent of the Sacred Heart in Roehampton (later Woldingham School) where several of her cousins, princesses of Luxembourg, were also enrolled.