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The county was named for Dr. William Wyatt Bibb, a physician from Elbert County who went on to serve in the United States Senate and House of Representatives before becoming the first elected Governor of Alabama.
Armistead worked for trucking companies for 20 years before becoming a staffer for H. Guy Hunt, the Governor of Alabama.
He was one of the attorneys of record for former Alabama Governor Don Siegelman during Siegelman's federal trial in the U.S. District Court for the Middle District of Alabama on charges of bribery, mail fraud, and obstruction of justice.
Governor Robert J. Bentley appointed Canfield to the Alabama Development Office in July 2011, succeeding Seth Hammett.
Alabama Governor Bob Riley urged his constituents to act as prayer warriors, and Georgia Governor Sonny Perdue designated a three-day prayer weekend that he cast as a spiritual battle.
Arthur P. Bagby (1794–1858), lawyer, governor of Alabama, and United States senator from Alabama
Charles S. McDowell (1871–1943), Charles Samuel McDowell, Jr., interim Governor of Alabama
Clement Comer Clay (1789–1866), Governor of Alabama 1835–1837, and U.S. Senator from Alabama 1837–1841
George S. Houston (1811–1879), American Democratic politician; 24th Governor of Alabama
His grandfather, Hugh Davis Merrill, was a state judge and Lieutenant Governor of Alabama.
Joseph F. Johnston (1843–1913), governor of Alabama, 1896–1900
Nathan Lee Miller (1866–unknown), ninth lieutenant governor of Alabama
Russell McWhortor Cunningham (1855–1921), American Democratic politician, acting Governor of Alabama, 1904–1905
President John F. Kennedy federalized the Alabama National Guard later the same day, which put them under the command of the President, rather than the Governor of Alabama.