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In 1842 he entered into correspondence with the leaders of the Tractarian movement in England, and some interesting letters have been preserved which were exchanged between him and Edward Pusey, William Ewart Gladstone and James Hope-Scott.
In 1847 he married Charlotte Harriet Jane Lockhart, daughter of John Gibson Lockhart and granddaughter of Sir Walter Scott, and, on her coming into possession of Abbotsford House six years later, he assumed the surname of Hope-Scott.
James Hope-Scott, a prominent barrister, who was the father of James Hope, 1st Baron Rankeillour (see the Baron Rankeillour for more information on this branch of the family).