James Wemyss, 5th Earl of Wemyss (1699–1756), grandson of the preceding, Scottish peer
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James Weams (1851–1911), aka James Wemyss, Durham comedian and singer/songwriter
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James Wemyss, Lord Burntisland (d. 1682), husband of Margaret Wemyss, 3rd Countess of Wemyss
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James Erskine Wemyss (1789–1854), grandson of the preceding, Scottish admiral and MP