Outside of football he was president of the YWCA and the YMCA in England, a director of Barclays Bank and Lord High Commissioner to the General Assembly of the Church of Scotland in 1907, 1908 and 1909.
Between 1867 and 1868 he was also Lord High Commissioner to the General Assembly of the Church of Scotland.
He was Lord High Commissioner to the General Assembly of the Church of Scotland, a Privy Councillor and one of the Committee of the Estates.
A lifelong member of the Church of Scotland, from 1970 to 1971 she became the first woman to serve as Lord High Commissioner to the General Assembly of the Church of Scotland.
He was created Marquess of Annandale in 1701, Lord High Commissioner to the General Assembly of the Church of Scotland in 1701 and 1711, Keeper of the Privy Seal of Scotland in 1702, and president of the Privy Council of Scotland from 1692 to 1695, 1702-4 and 1705-6.
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In Scotland, the Lord High Commissioner to the General Assembly of the Church of Scotland ranks immediately below the sovereign or consort (depending on their respective sex), but only when the General Assembly is in session, and immediately followed by the Moderator of the General Assembly of the Church of Scotland.
He went on to become Lord High Commissioner to the General Assembly of the Church of Scotland and was appointed a Knight of the Thistle.