In 1662, she was engaged to Duke Charles IV of Lorraine, who had been banned by the Pope for deserting his spouse Nicolette of Lorraine for Beatrice de Cousance, but the engagement was broken when he married Marie Louise d'Aspremont (1651–1693) in 1664.
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The bride was Marie Louise d'Aspremont (1652–1692), the eighteen-year-old daughter of Charles d'Aspremont-Lynden, Count of Rekem, and Marie Françoise de Mailly.
During the War of the Austrian Succession in 1743, he was Commandander-in-Chief of the Imperial and Piedmontese armies in Italy.