The first settlement in what is today the municipality of Doctor González took place in October 21, 1694, founded by Spanish settlers as Hacienda de Ramos, the history of the region where the municipality is now located lies within the Salinas Valley, a historic region in the former New Kingdom of León which extended throughout the Salinas River comprising several municipalities in northern Nuevo León, an important region during the colonization of Nuevo León.
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Francisco Ignacio Elizondo Villarreal, (Salinas Valley, New Kingdom of León, New Spain, March 9, 1766 - San Marcos, Texas, New Spain, September 2, 1813), was a New Leonese royalist general, mostly known for his victorious plot to seek to capture important insurgency precursors of the Mexican War of Independence such as Miguel Hidalgo, Ignacio Allende, and Juan Aldama in Baján, Coahuila in 1811.