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The station is located on Rama I Road to the west of Pathum Wan intersection, where the National Stadium, MBK Center, Siam Discovery Center, Bangkok Art and Culture Centre and Siam Square are situated and all linked to the station by skybridge.
It runs eastward from the National Stadium Station in Pathum Wan District over Rama I Road and interchanges with the Sukhumvit Line at Siam BTS Station, then turns southward, following Ratchadamri, Si Lom, Narathiwat Ratchanakharin and Sathon Roads to Taksin Bridge where it crosses the Chao Phraya River and terminates at Bang Wa Station in Phasi Charoen District.