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Wishing to develop a better process for the production of alkali than the Leblanc process, he joined in partnership with John Brunner, who also worked for Hutchinson, to improve the ammonia-soda process, building a factory for this purpose at Winnington.
Solvay, New York and Rosignano Solvay, the locations of the first Solvay process plants in the United States and in Italy, are also named after him.