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5AD personalities of the 1960s and 1970s included Bob Francis, Alec Macaskill, Keith Conlon, Barry Ion who also voiced the hilarious Peter Plus character, Tony Pilkington, Malcolm T. Elliott, Sam Galea, Ken Dickins, John Vincent, Bob Byrne, Dean Jaensch, Jeff Sunderland, Kevin Crease, and many others.
While in Adelaide, Ion began working for 5AD and formed a radio breakfast duo with Tony Pilkington called "Bazz and Pilko".