X-Nico

unusual facts about Walter Reppe


1,4-Butanediol

This type of acetylene-based process is illustrative of what is known as "Reppe chemistry", after German chemist Walter Reppe.


Koch reaction

Usage of a Ni(CO)4 catalyst with CO and water as a nucleophile is known as the Reppe carbonylation, and there are many variations on this type of metal-mediated carbonylation used in industry, particularly those used by Monsanto and the Cativa processes, which convert methanol to acetic acid using acid catalysts and carbon monoxide in the presence of metal catalysts.


see also