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In 1015, his peaceful austerity was interrupted by the death of Vladimir I of Kiev, and the subsequent fratricidal war for the throne between Vladimir's sons Yaroslav and Sviatopolk, and Anthony returned to Mount Athos.
He acquired the reputation of well-educated scholar and upon the death of Metropolitan Theopemptus in 1049, Hilarion was proclaimed the metropolitan of Kiev by Yaroslav the Wise, the Grand prince of Kiev, who thus challenged the old Byzantine tradition of placing Greeks on the episcopal sees.