On the 23 May 1877, Williams met his future wife Rose Harriette, eldest daughter of Robert Thompson Crawshay the ironmaster of Cyfarthfa Castle in Merthyr.
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They had two sons, Eliot Crawshay-Williams who was also a Member of Parliament and Leslie Crawshay.
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Although they moved to Eastbourne for some time, Williams and his family moved back to South Wales in 1889 and set up home at Plas Coed-y-Mwster, a mansion in Coychurch, Bridgend.
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