Hynes is founder of Nativity Preparatory School in Boston and Nativity Preparatory School of New Bedford, as well as co-founder of Paraclete in South Boston with Sister Ann Fox.
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In 2005, Hynes narrowly beat a primary challenge from State Senator John L. Sampson who won 37 percent of the vote to Hynes' 41 percent.
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Hynes has been criticized for alleged reluctance in prosecuting cases of sexual abuse against children in ultra-Orthodox Jewish communities, which make up a significant segment of Brooklyn.
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Hynes was ranked as number 1 on a "Top 7 Criminals And Bad Boys" list in Heeb magazine for the Jewish year 5773 (2012-2013), partly due to going easy on haredi criminals, especially pedophiles.