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He distinguished himself in the Battle of Turin (1706) and received command of the fortification of Mantua.
Following the departure of Vendôme to shore up the shattered army in the Flanders, Prince Eugène and the Duke of Savoy inflicted a heavy loss on the French under the duc d'Orléans and Ferdinand de Marsin at the Battle of Turin, driving the French out of Italy by the end of the year.