Infatuated with an actress (Mademoiselle Fleury), he was thwarted in his intention of marrying her and met his rival, the count of Bourbon-Busset, in a duel.
They made their home at the Chateau de Busset, where she made many renovations including a covered arcade on the ground floor and a gallery in the east wing.
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She married her second husband, Philippe de Bourbon, Seigneur de Bourbon-Busset on 3 February 1530.
Her twin daughters, Joséphine (1796–1844) and Charlotte (1796–1818), married respectively Ferdinand de Chabot, prince de Leon and afterwards duc de Rohan, and François, comte de Bourbon-Busset.
Bourbon-Busset | Busset |
Anne's maternal grandmother Francoise Eulalie Marie Madeleine de Burbon-Busset was a direct descendant of the sixth son of King Louis IX of France, Robert, Count of Clermont.
She was born of a cadet branch of the Bourbon-Busset: her father was Georges, Count of Lignières, and her mother Marie Jeanne de Kerret de Quillien.