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The horizon problem is a problem with the standard cosmological model of the Big Bang which was identified in the late 1960s, primarily by Charles Misner.
In the context of general relativity, he is best known for his development (with Stanley Deser and Charles Misner) of the ADM formalism, roughly speaking a way of describing spacetime as space evolving in time, which allows a recasting of Einstein's theory in terms of a more general formalism used in physics to describe dynamical systems, namely the Hamiltonian formalism.
In the context of general relativity, he is best known for his development (with Richard Arnowitt and Charles Misner) of the ADM formalism, roughly speaking a way of describing spacetime as space evolving in time, which allows a recasting Einstein's theory in terms of a more general formalism used in physics to describe dynamical systems, namely the Hamiltonian formalism.