Vaughan was educated at Rugby School, where he entered on 22 January 1788, and at Merton College, Oxford, matriculating on 26 October 1791.
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With them, he sailed for the Volga in November, was shut out by the ice, and had to spend the winter on the desert island of Kulali, but eventually arrived at Astrakhan in April 1806, reaching England by way of St Petersburg on 11 August 1806.
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