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Home was born at Dalkeith House, Midlothian (the seat of his maternal grandfather), the son of Alexander Home, 10th Earl of Home, by Lady Elizabeth Scott, daughter of Henry Scott, 3rd Duke of Buccleuch.
Buccleuch was born at Dalkeith House, Midlothian, Scotland, the fifth child of seven, and second son of Charles Montagu-Scott, 4th Duke of Buccleuch, and the Honourable Harriet Katherine Townshend, daughter of Thomas Townshend, 1st Viscount Sydney and Elizabeth Powys.