In 1793, when he held the rank of a lieutenant, he was a member of the Macartney Embassy to China, led by Lord Macartney, who was his mother's cousin.
The first internal passports in South Africa were introduced on 27 June 1797 by the Earl Macartney in an attempt to exclude all natives from the Cape Colony.
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Her sisters were Lady Mary Stuart (c. 1741–1824), who married James Lowther, later the 1st Earl of Lonsdale; Lady Anne Stuart (born c. 1745), who married Lord Warkworth, later the 2nd Duke of Northumberland; Lady Jane Stuart (c. 1748–1828), who married George Macartney, later the first Earl Macartney; and Lady Caroline Stuart (before 1763–1813), who married The Hon.