Vivian was a county councillor for Glamorgan from 1889 to 1898, He was High Sheriff of Cornwall in 1889 and was awarded the CB in 1894.
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On the death of his great uncle, Francis Enys in 1821 he inherited the Enys Estate, near Penryn, Cornwall and was appointed High Sheriff of Cornwall in 1824.
John Tremayne Babington (1891–1979), later John Tremayne Tremayne, British Air Marshal and High Sheriff of Cornwall in 1954
John Hearle Tremayne (1780–1851), Cornish MP and High Sheriff of Cornwall in 1831