Through either the deaths or morganatic marriages of his elder brothers, George was the head of the Russian branch of the House of Beauharnais.
In 1869, he married Daria Konstantinowa Opotschinina, the granddaughter of Mikhail Kutuzov: she was made countess of Beauharnais (died 1870 in childbirth); and in 1878 to Zeneïde Dmitrijewna Skobelew (also known as Zina) (died 1899), sister to the Russian general Mikhail Skobelev.
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