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The second son of James Blount, 6th Baron Mountjoy, Charles became the most notable of the later holders of the barony, inheriting the title in 1594 on the death of his unmarried elder brother William.
Sir James Blount (died 1493) (sometimes spelt Blunt) was commander of the English fortress of Hammes, near Calais.
Henry Bennet lauded him in 1561, mentioning also his patronage of Eliseus Bomelius, and the same year Jean Veron dedicated to him an anti-papal tract.