Two of his large-scale paintings — altar pieces The Deposition from the Cross (1781) and The Apparition of Our Lord to St Thomas (1784) have been preserved in Wolverhampton, and can be seen today at St John's church and at St Peter & St Paul's Roman Catholic church.
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Other customers were Mrs Elizabeth Montagu (1718–1800), Sir Sampson Eardley, 1st Baron Eardley(1744–1824); possibly, Beilby Porteus, the Bishop of Chester and a well-known abolitionist (1731–1809); Lord Macclesfield and, possibly, Isaac Hawkins Browne.
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George Barney was the son of Joseph Barney, drawing master at the Royal Military Academy, Woolwich, England, and Jane, née Chandler (Chambers, according to British sources).