Under Prince Andrew Báthory, he participated in the Battle of Sellenberk in 1599, where the Transyvanian army suffered a severe defeat from Michael the Brave, ruler of Wallachia.
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Her father was Prince Grégoire Bibesco-Bassaraba, a son of Wallachian Prince Gheorghe Bibesco and Zoe Mavrocordato-Bassaraba de Brancovan.
Menaced by the growing privileges of boyars and threatened to lose land grants or be turned into serfs, the Wallachian seimeni rebelled in 1655, being crushed after Prince Constantin Şerban enlisted the help of George II Rákóczi, Prince of Transylvania, as well as that of Moldavia's Voivode Gheorghe Ştefan.