The song debuted on the Download Chart at number twenty-five, later peaking at number fifteen.
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"Lovelight" features a music video that was directed by Jake Nava and filmed in Vienna, Austria during a break from Williams' European Close Encounters Tour.
Her music hall repertoire included "A Schoolgirl's Holiday", "We've been chums for fifty years", "When the Harvest Moon is Shining", "Silver Bell", "You do Look Well in Your Old Dutch Bonnet", "Queen of the Cannibal Isles", "Never Mind", "When I see the Lovelight Gleaming", and especially "Nellie Dean" - written by Henry W. Armstrong - which an audience first heard her sing in 1907.
McKernan's final performance of "Lovelight" – complete with extended vocal raps – occurred at the Lyceum Theatre, London, during the Europe '72 tour.