In 1802, Tsar Alexander I encouraged resettlement of religious minorities to the so-called 'Milky Waters" (Molochnye Vody): the region of Molochnaya River (around Melitopol in today's southern Ukraine). This was motivated by the desire both to quickly populate the rich steppe lands on the north shore of the Black and Azov Seas, and to prevent the "heretics" from contaminating the population of the heartland with their ideas.
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Along with a number of other villages in northwestern Azerbaijan, Slavyanka was settled in 1844 by the Doukhobors, members of a Pacifist dissenter Christian group resettled to Transcaucasia by Nicholas I from the Molochna River settlements in today's Zaporizhia Oblast of the Ukraine.