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In 1573, when ambassadors from Poland came to see the duke of Anjou, she publicly replied to them in Latin on behalf of the queen-mother and her speech took on those of René de Birague and the comte de Chverny, who replied on behalf of Charles IX and the duke of Anjou.
Henri d'Angoulême took a major role in the two extended military battle against Huguenot strongholds during the height of the French Wars of Religion, engaging in the massive Siege of La Rochelle (1572–1573), organized by the Duke of Anjou, future Henry III of France, and leading the five-year Siege of Ménerbes (1573–1578), fought at a citadel in the Luberon foothills cherished by Pope Pius V.
He was charged, in 1567, with the command of the Loire Valley, served under the Duke of Anjou and was killed at the siege of Melle, March 25, 1577, at the moment when the city fell.
Louis III (25 September 1403 – 12 November 1434) was titular King of Naples 1417–1426, Count of Provence, Forcalquier, Piedmont, and Maine and Duke of Anjou 1417–1434, and Duke of Calabria 1426–1434.
In 1576 he accompanied the Duke of Anjou on an expedition into the Netherlands in order to regain the former Rosny estates, but being unsuccessful he attached himself for a time to the Prince of Orange.
His youngest brother, Gaston de France, titled at birth as Duke of Anjou as was customary for the third son, was born in 1608.
Philippe-Charles of France, Duke of Anjou (Philippe-Charles de France, duc d'Anjou; 5 August 1668 - 10 July 1671, 2 years, 11 months, 5 days) was the fifth child and second son of Louis XIV of France, King of France and his wife, the Infanta Maria Teresa of Spain, and as such was a Fils de France.
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Philippe-Charles de France, born at the Château de Saint-Germain-en-Laye, was the second son of the Louis XIV, and titled duc d'Anjou at birth, title previously held by his uncle, Philippe de France, duc d'Orléans, younger brother of Louis XIV.