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To prevent the breakup of the estates, Edmond ceded the Dino property to his second son Alexandre (husband of Valentine de Sainte-Aldegonde), while his elder son Louis was styled Duke of Valençay and later inherited the Duchy of Sagan.
His complete works, edited by Lacroix and Quinet, were published at Brussels in 7 volumes (1855–1859), and his religious and theological writings, edited by Van Toorenenbergen, at The Hague, in 4 volumes (1871–1891).
On 8 October 1839 she married Alexandre Edmond de Talleyrand-Périgord, son of Edmond de Talleyrand-Périgord and Princess Dorothea of Courland, at the Château de Beauregard at Cellettes (Loir-et-Cher), her mother's property.