In 1860 the Central Academy was upgraded and renamed Prince of Wales College (PWC) in honour of a visit to the colony that year by the Prince of Wales, later to become King Edward VII.
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Van Miltenburg attended Mavo in Utrecht from 1979 until 1984 when she studied for a year at the Prince of Wales College in Vancouver.
Achimota, originally known as the Prince of Wales College and School, was formally opened on 28 January 1927 by the then Governor of the Gold Coast, Sir Frederick Gordon Guggisberg.
Prince of Wales' College was founded in 1876 by Sir Charles Henry de Soysa (along with Princess of Wales' College, Moratuwa) who was a famous 19th century Sri Lankan philanthropist.