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His father was the fourth son of Robert Alexander Dalzell, 6th Earl of Carnwath and his mother the daughter of John and Amelia (Ryerse) Harris of Eldon House, London, Ontario, Canada.
A representative peer for Scotland, he died while walking from his home, Carnwath House, Fulham, to the House of Lords.
Robert Dalzell, 5th Earl of Carnwath, (1687–1737), known as Sir Robert Dalzell, 3rd Baronet from 1689 until 1702, was a Scottish nobleman and Jacobite supporter during James Stuart, the Old Pretender's, unsuccessful rebellion in 1715 known as the Fifteen or Lord Mar's Revolt.
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He married, fourthly, Margaret Vincent, daughter of Thomas Vincent and Isabel Packer, on 19 June 1735 at Worksop, Nottinghamshire.
Lieutenant-General Robert Alexander Dalzell, 6th Earl of Carnwath, (1768–1839), was a Scottish nobleman and soldier.
He left two sons, Francis and James, and two daughters; Anne Mary, the eldest, married General Robert Dalzell (1662–1758).