The prefecture covered the south-western part of the agglomeration of Athens, several islands in the Saronic Gulf (Salamis, Aegina, Agkistri, Poros, Hydra, Dokos, Spetses, Spetsopoula), Methana and Troizina on the Peloponnese peninsula, and the islands of Kythira and Antikythera south of the Peloponnese.
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It begins at Agioi Theodoroi and stretches eastward to the cape south of the village of Pachi in Megara and a small strait near Salamis Bay, and south to the area around Lamprino on the island of Salamis.
The mountain offers panoramic views of the mountains northeast of Parnitha, Penteli to the east, the Ymittos to the southeast, the Aigaleo to the south and another to the west; from its summit, one can also see the Thriasian Plain, the Saronic Gulf including the islands of Salamina, Aigina and the North, the South Euboean Gulfs and island of Euboea, and most of central and northern Greater Athens.