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Nikolaus married the English Sarah Frederica Caroline Child Villiers (1822–1853), daughter of George Child Villiers, 5th Earl of Jersey and Lady Sarah Sophia Fane.
She was immortalized as Zenobia in Disraeli's novel Endymion.
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Her own affairs, though conducted discreetly, were said to be numerous: Henry John Temple, 3rd Viscount Palmerston, was thought to be one of her lovers.