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He fled to Gibraltar in February 1814, and was delivered up by the acting governor, Sir George Don, to the Spanish authorities, but released in the following year on the reclamation of the British cabinet, which disavowed the conduct of the governor.
From 1803 to 1805 Lord Cathcart was commander-in-chief in Ireland, and in the latter year he was sent by Pitt to supersede Sir George Don in command of the 14,000 strong British expedition to Hanover.