In 1837, at London, he married Anne Easthope (1808-1869), the eldest daughter of his business partner Sir John Easthope, 1st Bt.
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The Bridgeman Baronetcy, of Ridley in the County of Chester, was created on 12 November 1773 for Orlando Bridgeman, Member of Parliament for Horsham and younger son of the 1st Baronet, of the Great Lever creation.
For over 50 years Copley has been the partner of John Hugh Chadwyck-Healey (born 1922), grandson of Charles Chadwyck-Healey, 1st Baronet.
Pollock was the fifth son of Mr George Pollock, fourth son of Sir Frederick Pollock (1st Baronet, of Hatton) (elder brother of Field Marshal Sir George Pollock, 1st Baronet, of The Khyber Pass).