Teofila Ludwika Zasławska was an heiress of the Ostrogski family, one of the great Ruthenian princely families of the Grand Duchy of Lithuania.
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Lubomirskis owned several palaces where they lived, all of them designed or redesigned by the royal architect Tylman van Gameren, including palaces in Lublin, Warsaw, Lubartów, and the Baranów Sandomierski Castle in Baranów.