The section of SR-33 between Knoxville and Tazewell, along with US 25E between Tazewell and Middlesboro, KY, was an inspiration for the song The Ballad of Thunder Road.
It tells the tale of "Lucas Doolin" (Robert Mitchum), a bootlegger during the 1950s who would deliver moonshine along local roads at excessive speeds to avoid "revenuers".
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The song in the movie soundtrack itself is a softer, more ballad-like version than the hit single recorded by Mitchum, and was sung by Randy Sparks.
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