After studies in the Real Colegio de San Carlos, on 23 July 1786 he earned a degree in law at the University of Saint Francis Xavier of Chuquisaca.
The news of the fall of Ferdinand VII in Spain caused great concern in the city, and in the University of Chuquisaca there were important debates about the legitimacy of the government.
Sucre's University (Universidad Mayor Real y Pontificia de San Francisco Xavier de Chuquisaca) is one of the oldest universities in the new world.
Once Republic was proclaimed by Simón Bolívar, the university became the main university of the new country.
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