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Juan Alonso Pimentel de Herrera (died Benavente, Spain on 7 January 1621) was a Knight of the Order of Santiago, Grandee of Spain, 5th Duke of Benavente at the death without issue of the 4th Duke, as he was the second son of the 3rd Duke, 8th Count of Mayorga, 3rd Count of Villalón, President of the Council of Italy, 15th Viceroy of Valencia, 25th Viceroy of Naples.
He was born in Mula, region of Murcia, a great-grandson of Luis de Zúñiga y Requesens and the son of Luis Fajardo Requesens y Zúñiga, Marqués de los Vélez, (1576–1631), the preceding Viceroy of Valencia, 1628–1631, deceased 1631, 4th Marqués de los Vélez.