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He was probably a pupil of Berengar of Tours, and became master (scholasticus) of the school at Le Mans; in 1091 he was made archdeacon and in 1096 bishop of Le Mans.
Liborius of Le Mans (c. 348–397) was the second Bishop of Le Mans.
His battles with Avesgaud, Bishop of Le Mans were heating up again and in 1025 Herbert made a night raid on the Bishop’s castle at Duneau causing Avesgaud to flee to the protection of his brother William Lord of Belleme.