The octahedron has eight faces, hence the prefix octa. The octahedron is one of the Platonic solids, although octahedral molecules typically have an atom in their centre and no bonds between the ligand atoms.
The design is reminiscent of the Sierpinski tetrix: placing four half-size tetrahedra corner to corner and adding an octahedron in the middle, a full-size tetrahedron is formed; this process can be repeated recursively to form larger and larger tetrahedra.