X-Nico

3 unusual facts about polythiophene


Polythiophene

As an approximation, the conjugated backbone can be considered as a real-world example of the "electron-in-a-box" solution to the Schrödinger equation; however, the development of refined models to accurately predict absorption and fluorescence spectra of well-defined oligo(thiophene) systems is ongoing.

The maturation of the field of conducting polymers was confirmed by the awarding of the 2000 Nobel Prize in Chemistry to Alan J. Heeger, Alan MacDiarmid, and Hideki Shirakawa "for the discovery and development of conductive polymers".

As an example of a static application, poly(3,4-ethylenedioxythiophene)-poly(styrene sulfonate) (PEDOT-PSS) product Clevios P (Figure 7) from Heraeus has been extensively used as an antistatic coating (as packaging materials for electronic components, for example).


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Organic field-effect transistor

OFETs employing many aromatic and conjugated materials as the active semiconducting layer have been reported, including small molecules such as rubrene, tetracene, pentacene, diindenoperylene, perylenediimides, tetracyanoquinodimethane (TCNQ), and polymers such as polythiophenes (especially poly(3-hexylthiophene) (P3HT)), polyfluorene, polydiacetylene, poly(2,5-thienylene vinylene), poly(p-phenylene vinylene) (PPV).


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