X-Nico

unusual facts about Aldol


Aldol

Alexander Borodin is also credited with the discovery of the Aldol reaction together with Wurtz.


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Aldol condensation

In industry the Aldox process developed by Royal Dutch Shell and Exxon, converts propylene and syngas directly to 2-Ethylhexanol via hydroformylation to butyraldehyde, aldol condensation to 2-ethylhexenal and finally hydrogenation.

Farinamycin

3,4-AHBAm is made via the aminoshikimate pathway from L-Aspartate-4-semialdehyde and Dihydroxyacetone phosphate via an enzyme catalyzed aldol condensation followed by ring formation.


see also