In 2004, on the occasion of the centenary of De Martino's death, the town of Palma Campania, the region of Campania and the province of Naples, celebrated his life with a festival and with the unveiling of a marble plaque on the facade of the Palazzo De Martino.
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In 1869, as a medical adviser of the Royal House, he assisted in childbirth Princess Margherita, Umberto I's wife and future queen, who gave birth to Victor Emmanuel III.
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