On 15 February 1975 Don Carlos married Dona Maríá las Nieves Castellano y Barón Marquesa de Almazán (b. 24 Sept. 1947) acquiring the title of Marqués de Almazán which had been created by Philip II of Spain in 1575.
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He took the solemn oath in front of the Knights and Dames of the Order in Manchester Cathedral in England.
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