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In 1712, two years after Mohun's Whig party had been heavily defeated in an election, the Duke of Hamilton gained the post of special envoy to Paris.
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But Mohun is best remembered for the events of 9 December of that year—a friend of Mohun's, an officer named Richard Hill, had fallen in love with the actress Anne Bracegirdle; however he thought himself, almost certainly erroneously, to face competition from actor William Mountfort.
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There he served under Charles Gerard, 2nd Earl of Macclesfield, the uncle of his former wife, and briefly served in France.
On 15 November 1712, Hamilton fought a celebrated duel with Charles, Lord Mohun, in Hyde Park, Westminster, in an episode narrated in Thackeray's The History of Henry Esmond.