On 22 July 2009, it was announced that Di Luca had tested positive for CERA on 20 and 28 May 2009, during the Giro d'Italia.
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During his time at Saeco-Longoni he lost the Vuelta al País Vasco on the last stage, a mountain time trial in which Andreas Klöden took the lead and the win.
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He recovered to compete in the 2006 Vuelta a España, winning the fifth stage and holding the lead (ceding it to Janez Brajkovič).
Luca Giordano | Luca Francesconi | Accademia di San Luca | Luca Signorelli | Luca Ronconi | Luca Turilli | Luca Toni | Pallithanam Luca Matthai | Luigi Luca Cavalli-Sforza | Luca Paolini | Luca Pacioli | Luca Cumani | Luca Cardelli | Danilo Dolci | Metropolitan Danilo I Petrović-Njegoš | Luca Pianca | Luca Marmorini | Luca Lombardi | Luca Guadagnino | Luca Beltrami | Giovanni Luca Conforti | Danilo Rea | Danilo I, Prince of Montenegro | Danilo Astori | The ''Communion of the Apostles'', by Luca Signorelli | Sergiu Luca | San Luca | Saint Danilo II | Rudy De Luca | ''Maria Anna of Neuburg on horseback'' by Luca Giordano |