Bourne was the son of the Revd R. B. Bourne and was educated at Eton College and at Christ Church, Oxford (BA 1863, BCL 1866, DCL 1871).
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George Hugh Bourne was a hymnodist, schoolmaster and warden, chaplain to the Bishop of Bloemfontein, and ultimately on the staff of Salisbury Cathedral as Sub-dean and Prebendary.
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